| Distance from | | Distance from |
| Stirling | | Kingston |
| | | |
| 0.0 | Highway 14 Junction (Stirling) | 138.1 |
| | | |
| 12.5 | Mill Street West Junction (Frankford) | 125.6 |
| | | |
| 21.1 | Highway 401 Interchange (To Toronto) | 117.0 |
| | | |
| 25.2 | Highway 2 East Junction (Trenton) | 112.9 |
| | | |
| 25.7 | Highway 2 West Junction (To Brighton) | 112.4 |
| | | |
| 29.6 | Wooler Road Junction (To Hwy 401) | 108.5 |
| | | |
| 41.3 | Prince Edward Roads 1 & 29 Junction (Consecon) | 96.8 |
| | | |
| 59.3 | Consecon Street Junction (Wellington) | 78.8 |
| | | |
| 69.6 | Highway 62 Junction (Current West Terminus of King's Hwy 33) | 68.5 |
| | | |
| 74.7 | Prince Edward Road 1 Junction (Warings Corners) | 63.4 |
| | | |
| 78.3 | Highway 49 Junction (Picton) | 59.8 |
| | | |
| 86.9 | Glenora Ferry Dock | 51.2 |
| | | |
| 86.9 | Adolphustown Ferry Dock | 51.2 |
| | | |
| 106.2 | Lennox & Addington County Road 21 Junction (To Napanee) | 31.9 |
| | | |
| 114.0 | Lennox & Addington County Road 7 Junction (Bath) | 24.1 |
| | | |
| 117.5 | Former King's Hwy 133 - L & A County Road 4 Junction (Millhaven) | 20.6 |
| | | |
| 130.1 | Collins Bay Road Junction (Current East Terminus of King's Hwy 33) | 8.0 |
| | | |
| 138.1 | Highway 2 Junction (Kingston) | 0.0 |
